Abstract

In a previous paper one of us (3) described a _ method for the determination of the alkalinity of sea water-then termed the buffer capacity of sea water. This method was very rapid, eliminated the need for a titration process, and was particularly advantageous when working under rigorous field conditions. However considerable difficulty was sometimes experienced in the preparation of color comparison standards from base-free sea water. The method was later improved by Mitchell and Rakestraw (2). The present paper deals with a modification of the original method. The glass electrode is used for the measurement of excess acid and gives a precision greater than that obtained with color standards. If suitable shelter is available the method may be performed as readily in the field as in the laboratory. Following is a description of the apparatus and the method used.

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